I'll begin by listing my top five in each category.
Best film:
1. Goldfinger
2. Living Daylight
3. Goldeneye
4. Casino Royale
5. From Russia with Love
Worst: Quantum of Solace, it was a real bummer!!
Best Bond:
1. Timothy Dalton
2. Sean Connery
3. Daniel Craig
4. Pierce Brosnan
5. George Lazenby
Worst: Roger Moore, he's nothing more than a joke to me!
Best Villains:
1. Sean Bean (Trevelyan)
2. Christopher Lee (Scaramanga)
3. Mads Mikkelsen (Le Chiffre)
4. Joseph Wiseman (Dr No)
5. Gert Fröbe (Goldfinger)
Worst? Has to be that cat petting Blofeld. The character is almost a parody off itself! It doesn't help that four different actors play the role either.
Best Bond girl:
1. Famke Janssen (was never in bed with Bond but boy did she try

2. Ursula Andress
3. Rosamund Pike
4. Halle Berry
5. Barbara Bach
Worst: Izabella Scorupco, she's annoying the entire movie! And not "sexy annoying", just annoying.
There's one more topic I think we can get into. If this is Daniel Craig's last film, who do you want to take his place?
I'd like to see Hugh Jackman! Even though he's an Aussie.